Search results for "electric [charge]"
showing 10 items of 729 documents
Short and long range order of Half-Heusler phases in (Ti,Zr,Hf)CoSb thermoelectric compounds
2016
Abstract The structural properties of (Ti,Zr,Hf)CoSb thermoelectric Half-Heusler compounds were investigated by synchrotron radiation based techniques. The short-range order, in particular the environment of the Co atoms, was studied by extended X-Ray absorption fine structure spectroscopy and the long range order by powder X-Ray diffraction. Structural models were obtained for the single phase materials TiCoSb0.85Sn0.15, ZrCoSb0.85Sn0.15, and HfCoSb0.85Sn0.15. These models were transferred for the phase-separated material Ti0.5Hf0.5CoSb0.85Sn0.15. As a result, proving that each Half-Heusler phase was well ordered, apart from the intermixing of Ti and Hf on its designated crystallographic l…
Performance of a thermoelectric module based on n-type (La0.12Sr0.88)0.95TiO3-δ and p-type Ca3Co4-xO9+δ
2020
Here, we present the performance of a thermoelectric (TE) module consisting of n-type (La0.12Sr0.88)0.95TiO3 and p-type Ca3Co4-xO9+δ materials. The main challenge in this investigation was operation of TE module in different atmosphere conditions, since n-type has its optimum TE-performance at reducing, while p-type at oxidizing conditions. The TE module was exposed to two different atmospheres and demonstrated higher stability in N2 atmosphere than in air. The maximum electrical power output decreased after 40 h when the hot side was exposed to N2 at 600 °C, while only 1 h at 400 °C in ambient air was enough to oxidize (La0.12Sr0.88)0.95TiO3 followed by a reduced electrical power output. T…
IMAGING OF DICHROISM IN PHOTOEMISSION ELECTRON MICROSCOPY AT NONMAGNETIC MATERIALS USING CIRCULARLY POLARIZED SOFT X-RAYS
2002
A new approach for investigations of circular dichroism in the angular distribution of photoelectrons (CDAD) is presented. The image contrast using a photoemission line of a certain material is combined with imaging of the angular distribution pattern using a photoemission electron microscope (PEEM). CDAD can be used to investigate pure scattering information by means of the same instrument in microscopically selected regions on a surface. The experiment combines angle-resolved XPS imaging with the indirect mapping of the local environment of atoms by means of CDAD holography. In a conventional photoelectron diffraction or photoelectron holography experiment, it is necessary to move the sa…
Photoemission from Pt(111)-(hex)-Rb and Pt(111)-(4×1)-RbO using polarised synchrotron radiation
2001
Abstract In various experiments it has been demonstrated that the circular dichroism in the angular distribution of photoelectrons (CDAD) is not only observed from oriented initial states (aligned adsorbed molecules or magnetised samples), but also arises as a consequence of the scattering of photoelectrons from the surrounding atoms in a solid or an adsorbate. In this work we will show first measurements performed at the SGM beamline of the Brazilian Synchrotron Light Source (LNLS) on a (4×1) superstructure of 1 ML RbO adsorbed on Pt(111). Measurements from the 4s core levels of Rb adsorbed at Pt(111) were also performed at the PM-III beamline at BESSY. The measured variations of the inten…
Phase separation as a key to a thermoelectric high efficiency
2012
This work elucidates the possible reasons for the outstanding, but never reproduced thermoelectric properties of the doped Ti(0.5)Zr(0.25)Hf(0.25)NiSn Heusler compounds. The structural investigations done via synchrotron X-ray diffraction measurements and scanning electron microscope measurements, which clearly show that the microstructure consists of three temperature stable C1(b) phases with possible semi-coherent interfaces, are presented. The exceptional thermoelectric properties are due to this intrinsic phase separation. It is possible to reproduce the high Figure of Merit values with ZT = 1.2 at 830 K. Furthermore, the influence of doping different elements on the Sn position in this…
Forecasting the diffusion of hydrogen EV refuelling infrastructures in Italy
2019
In Italy the electric vehicle revolution is arrived but it still has difficulties to take off. At the moment hybrid technology would seem the most quoted, due especially to range anxiety. The aim of this work is to understand if the fuel cell technology can find place in Italy. The possibility to use fuel cell to storage electric energy is quite interesting: the charging times will be reduced, and heavy passenger transportation should be easily faced. Basing on the existing history and analysis of the information accessible, this paper addresses the existing e-mobility scenario in Italy and predicts the cities in which a hydrogen refuelling infrastructure should be more remunerative, in ord…
Long-lived dynamic heterogeneity in a relaxor ferroelectric
1998
The polydispersive dielectric response of the relaxor ferroelectric lead magnesium niobate was investigated using nonresonant spectral hole-burning experiments. Using large alternating electric fields, specific parts of the relaxation-time distribution could be addressed selectively. This provides evidence for the dynamic heterogeneity of the dipolar reorientation process. The refilling of single as well as of double holes was much slower than the time scale set by the pump frequencies. Upon refilling, the holes exhibited no signs of spectral broadening. The present findings suggest a speedup of polarization response associated with a domain-wall depinning that is induced by the hole-burnin…
Fractal Dimension Logarithmic Differences Method for Low Voltage Series Arc Fault Detection
2021
Series arc faults introduce singularities in the current signal and changes over time. Fractal dimension can be used to characterize the dynamic behaviour of the current signal by providing a degree of signal chaos. This measure of irregularity exhibits changes in signal behaviour that can suitably be used as a basis for series arc fault detection. In this paper, an efficient low voltage series arc fault detection method based on the logarithmic differences of the estimate of the fractal dimension of the current signal using the multiresolution length-based method is presented. The discrete wavelet transform and the hard thresholding denoising with the universal threshold are also used. Exp…
Influence of a nano phase segregation on the thermoelectric properties of the p-type doped stannite compound Cu(2+x)Zn(1-x)GeSe4.
2012
Engineering nanostructure in bulk thermoelectric materials has recently been established as an effective approach to scatter phonons, reducing the phonon mean free path, without simultaneously decreasing the electron mean free path for an improvement of the performance of thermoelectric materials. Herein the synthesis, phase stability, and thermoelectric properties of the solid solutions Cu_(2+x)Zn_(1–x)GeSe_4 (x = 0–0.1) are reported. The substitution of Zn^(2+) with Cu^+ introduces holes as charge carriers in the system and results in an enhancement of the thermoelectric efficiency. Nano-sized impurities formed via phase segregation at higher dopant contents have been identified and are l…
INFLUENCE OF THE CHEMICAL POTENTIAL ON THE CARRIER EFFECTIVE MASS IN THE THERMOELECTRIC SOLID SOLUTION Cu2Zn1-xFexGeSe4
2013
In this paper, we describe the synthesis and characterization of the solid solution Cu 2 Zn 1-x Fe x GeSe 4. Electronic transport data have been analyzed using a single parabolic band model and have been compared to Cu 2+x Zn 1-x GeSe 4. The effective mass of these undoped, intrinsically hole conducting materials increases linearly with increasing carrier concentration, showing a non-parabolic transport behavior within the valence band.